Thermoluminescence, electron paramagnetic resonance, and structural characterization of natural prehnite for high-dose radiation dosimetry

Gomes M.B.; Gonzales-Lorenzo C.D.; Rocca R.R.; Ramirez F.N.; Cuevas-Arizaca E.E.; Silva-Carrera B.N.; Gundu Rao T.K.; Cano N.F.; Chubaci J.F.D. · Journal of Physics and Chemistry of Solids (2026) · DOI: 10.1016/j.jpcs.2026.113519

Resumen

Natural prehnite was evaluated as a thermoluminescence (TL) material for high-dose dosimetry. XRF identified SiO2, Al2O3, and CaO as major constituents. Prehnite samples annealed between 200 and 800 °C (1 h) were examined by XRD and Rietveld analysis, confirming prehnite as the majority phase and revealing calcite and vaterite after heating. The 600 °C sample provided the highest TL yield and was selected for detailed study. Fading tests showed a ∼40 % loss in the 240/350 °C peaks over 5.42 days (130 h), followed by signal stability. Dose–response demonstrated, for the 245 peak and 325 °C, a linear region in the 0.1–2 kGy and 0.5–20 kGy range, respectively, with saturation occurring between 30 and 100 kGy. Kinetic parameters were obtained using TM-Tstop, initial-rise, and variable-heating-rate methods; glow-curve deconvolution resolved five TL components. TL spectra display an intense band near 530 nm and a weak 550 nm band, suggesting two main recombination centers.

Instituciones: Universidad Nacional de San Agustín de Arequipa; Universidad Nacional de Piura; Universidad Católica Sedes Sapientiae; Universidad Católica de Santa María