Cd2+ Detection by an Electrochemical Electrode Based on MWCNT-Orange Peel Activated Carbon

Beas-Bernuy L.C.; Cardenas-Riojas A.A.; Calderon-Zavaleta S.L.; Quiroz-Aguinaga U.; La Rosa-Toro A.; López E.O.; Asencios Y.J.O.; Baena-Moncada A.M.; Muedas-Taipe G. · ACS Omega (2023) · DOI: 10.1021/acsomega.3c05154

Resumen

This study reports the development of a new electrochemical sensor based on a carbon paste electrode (CPE) composed of biomass-based orange peel activated carbon (ACOP) and multiwalled carbon nanotubes (MWCNTs), and this composite is used for the electrochemical detection of cadmium ions (Cd2+). The ACOP/MWCNT composite was characterized by FTIR, Raman, and electrochemical impedance spectroscopy. The electrochemical evaluation of Cd2+ was performed using square wave and cyclic voltammetry. The ACOP/MWCNT-CPE electrochemical sensor exhibited a coefficient of determination r2 of 0.9907, a limit of detection of 0.91 ± 0.79 μmol L-1, and a limit of quantification of 3.00 ± 2.60 μmol L-1. In addition, the developed sensor can selectively detect Cd2+ in the presence of different interferents such as Zn2+, Pb2+, Ni2+, Co2+, Cu2+, and Fe2+ with a relative standard deviation (RSD) close to 100%, carried out in triplicate experiments. The ACOP/MWCNT-CPE presented high sensitivity, stability, and reproducibility and was successfully applied for the detection of Cd2+ in river water samples with recovery rate values ranging from 97.33 to 115.6%, demonstrating to be a very promising analytical alternative for the determination of cadmium ions in this matrix.

Instituciones: Universidad Nacional de Ingeniería