Arsenic Removal from Drinking Water in Huanuara, Peru, Using Metalworking Residues: Characterization and Optimization

Costa Gil C.R.; Mamani López E.P.; Avendaño Cáceres E.O.; Vargas Conde E.V.; Flores Cotrado N.; Salazar Delgado D.M.; Quispe Jiménez O.A. · Processes (2025) · DOI: 10.3390/pr13041190

Resumen

Arsenic contamination in drinking water poses a critical environmental and public health threat, particularly in rural areas such as Huanuara, Peru, where concentrations exceed the 10 µg·L−1 limit established by the World Health Organization (WHO). This study explores the potential use of iron-rich metalworking residues as an alternative adsorbent. Characterization using Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM–EDS), X-ray Diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis revealed a specific surface area of 0.7469 m2·g−1, with magnetite (Fe3O4) and metallic iron (Fe0) as the predominant phases. Arsenic concentrations were quantified by Inductively Coupled Plasma Mass Spectrometry (ICP–MS). A batch reactor system treated 16 L per cycle under conditions of 293–298 K and 95.46 kPa. Adsorption parameters were optimized using a Central Composite Rotatable Design (CCRD), with adsorbent mass (31.72–88.28 g) and contact time (4.17–9.83 h) as variables. Under optimal conditions (80 g, 9 h), 99.07% arsenic removal was achieved, reducing concentrations from 530.03 µg·L−1 to ≤4.91 µg·L−1. The quadratic regression model (R2 = 0.90, p = 0.0006) was validated by ANOVA (p < 0.05; F = 22.02). These results demonstrate that metalworking residues offer a scalable and sustainable solution for arsenic remediation, supporting circular economy principles and decentralized water treatment.

Instituciones: Universidad Nacional Jorge Basadre Grohmann